Reaction operator in the main equation of spin chemistry
- Autores: Purtov P.A.1,2
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Afiliações:
- Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Edição: Volume 43, Nº 2 (2024)
- Páginas: 3-8
- Seção: Элементарные физико-химические процессы
- URL: https://cardiosomatics.orscience.ru/0207-401X/article/view/674981
- DOI: https://doi.org/10.31857/S0207401X24020016
- EDN: https://elibrary.ru/WJASAT
- ID: 674981
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Resumo
In our previous works, using an exactly solvable model as an example, we demonstrated the validity of the reaction operator in the basic equation of spin chemistry. However, in these works, only recombination from the singlet state was considered. Although the general relations allowed us to consider the general case. In the present paper, such a general case is analyzed. The radical pair comes into contact in a mixed singlet-triplet state, and recombination proceeds from both the singlet and triplet states. The result obtained fully corresponds to the basic equation of spin chemistry.
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Sobre autores
P. Purtov
Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Autor responsável pela correspondência
Email: purtov@kinetics.nsc.ru
Rússia, Novosibirsk; Novosibirsk
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Nota
Х Международная конференция им. В.В. Воеводского “Физика и химия элементарных химических процессов” (сентябрь 2022, Новосибирск, Россия).