Reaction operator in the main equation of spin chemistry

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Дәйексөз келтіру

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Аннотация

In our previous works, using an exactly solvable model as an example, we demonstrated the validity of the reaction operator in the basic equation of spin chemistry. However, in these works, only recombination from the singlet state was considered. Although the general relations allowed us to consider the general case. In the present paper, such a general case is analyzed. The radical pair comes into contact in a mixed singlet-triplet state, and recombination proceeds from both the singlet and triplet states. The result obtained fully corresponds to the basic equation of spin chemistry.

Толық мәтін

Рұқсат жабық

Авторлар туралы

P. Purtov

Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Хат алмасуға жауапты Автор.
Email: purtov@kinetics.nsc.ru
Ресей, Novosibirsk; Novosibirsk

Әдебиет тізімі

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Ескертпе

Х Международная конференция им. В.В. Воеводского “Физика и химия элементарных химических про­цессов” (сентябрь 2022, Новосибирск, Россия).


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