Synthesis and structural features of Co(II) compounds with 3-arylidene-1-pyrroline derivatives and monocarboxylic acids anions

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Abstract

A series of acetate and trifluoroacetate compounds of cobalt(II) with derivatives of 3-arylidene-1-pyrrolines (X-L; X = Cl, OH) as N-donor ligands was synthesized. Varying the synthesis and crystallization conditions made it possible to obtain coordination compounds of various compositions and structures: a tetranuclear complex based on a cubane fragment {Co4(OH)4}4– — [Co4(OH)4(Cl–L)4(OAc)4] (I), a 1D-polymer complex [Co(H2O)(Cl–L)2(CF3COO)1.167(OAc)0.833]n (II) or a molecular complex [Co(OH–L)2(OAc)2] (III). The synthesized compounds were characterized by X-ray diffraction, IR spectroscopy and CHN analysis. The structure and crystal packing of the obtained complexes were analyzed in detail, the main structure-forming non-covalent interactions in crystals were identified.

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About the authors

Yu. K. Voronina

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: juliavoronina@mail.ru
Russian Federation, Moscow

O. V. Zvereva

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Russian Federation, Moscow; Moscow

M. A. Shmelev

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Russian Federation, Moscow

E. N. Zorina-Tikhonova

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Russian Federation, Moscow

A. V. Rogachev

MIREA — Russian Technological University

Email: juliavoronina@mail.ru
Russian Federation, Moscow

A. A. Sidorov

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Russian Federation, Moscow

I. L. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Russian Federation, Moscow

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Supplementary files

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2. Fig. 1. Structure of the molecule (a) and fragment of the crystal packing (b) of compound I.

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3. Fig. 2. Structure of the monomer fragment (a), fragment of the polymer chain (b) and fragment of the crystal packing (c) of coordination polymer II.

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4. Fig. 3. Structure of the complex (a) and a fragment of the crystal packing (b) of complex III.

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5. Scheme 1. Synthesis of complexes I–III.

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