Analysis of Properties of Polymer Composites with Various Types of Fillers
- Authors: Yerofeyev V.T.1,2, Afonin V.V.3, Zotkina M.M.3, Stenechkin K.S.1, Tyuryakhina T.P.2, Lazarev A.V.2
-
Affiliations:
- National Research Moscow State University of Civil Engineering
- Scientific-Research Institute of Building Physics of RAACS
- National Research Mordovia State University
- Issue: No 1-2 (2024)
- Pages: 100-109
- Section: Modern concretes
- URL: https://cardiosomatics.orscience.ru/0585-430X/article/view/635979
- DOI: https://doi.org/10.31659/0585-430X-2024-821-1-2-100-109
- ID: 635979
Cite item
Open Access
Access granted
Abstract
The processes of structure formation of composite building materials (KSM) on different polymer binders are presented. It is shown that one of the most significant components of KSM are fillers, which help to improve their structural and operational characteristics. This work is devoted to the analysis of the results of an experimental study of the properties of epoxy composites with fillers having various elastic-plastic and strength properties. The research was carried out in three stages: at the first stage, studies were conducted aimed at assessing the influence of the nature of the filler on the curing processes of KSM; at the second, the influence of the type of filler and its quantitative content on the strength of composites was established, at the third, compositions were optimized using fillers with different indicators of grain composition and elastic-plastic properties. Powders of glass, dolomite, thermolite, and diatomite were considered as fillers at the first and second stages of the research, and powders of glass, ceramics, and chalk were considered at the second stage. The research at the third stage was carried out using mathematical methods of experiment planning with the construction of a planning matrix for a complete factor experiment and the determination of the values of the response functions relative to the encoded factors. The physico-mechanical properties, degree of curing, and chemical resistance of filled epoxy CCM have been established. On the basis of artificial neural networks, the maximum properties of the studied composites with fillers were determined. An assessment of structural properties based on rank correlation is also proposed. The results of the research can be used to predict the properties of KSM, as well as to clarify the extreme parameters of the properties. The dependences of changes in the properties of polymer composites on the surface characteristics, the dispersion of fillers and the degree of filling were established; preferred fillers for epoxy composites were determined; fillers were determined to assess the effect of elastic surface properties of composites, allowing to improve the strength and deformability of polymer composites; regression models were obtained based on a complete factorial experiment; an assessment of the «structural stability» of the studied composites using Pearson, Kendall, Spearman rank correlation; On the basis of artificial neural networks, the extreme properties of the studied composites with fillers were determined, neural networks.
Full Text
About the authors
V. T. Yerofeyev
National Research Moscow State University of Civil Engineering; Scientific-Research Institute of Building Physics of RAACS
Author for correspondence.
Email: erofeevvt@bk.ru
Doctor of Sciences (Engineering)
Russian Federation, Moscow; MoscowV. V. Afonin
National Research Mordovia State University
Email: vvafonin53@yandex.ru
Candidate of Sciences (Engineering)
Russian Federation, SaranskM. M. Zotkina
National Research Mordovia State University
Email: zotkina.mm@yandex.ru
Candidate of Sciences (Engineering)
Réunion, SaranskK. S. Stenechkin
National Research Moscow State University of Civil Engineering
Email: stenechkina522@mail.ru
Candidate of Sciences (Engineering)
Russian Federation, MoscowT. P. Tyuryakhina
Scientific-Research Institute of Building Physics of RAACS
Email: Kitana1908@mail.ru
Candidate of Sciences (Engineering)
Russian Federation, MoscowA. V. Lazarev
Scientific-Research Institute of Building Physics of RAACS
Email: laz@mail.ru
Candidate of Sciences (Engineering)
Russian Federation, MoscowReferences
- Karpenko N.I., Karpenko S.N., Yarmakovsky V.N., Erofeev V.T. On modern methods of ensuring the durability of reinforced concrete structures. ACADEMIA. Arhitektura i stroitel’stvo. 2015. No. 1, pp. 93–102. (In Russian).
- Bobryshev A.N., Erofeev V.T., Kozomazov V.N. Polimernye kompozicionnye materialy [Polymer composite materials: textbook]. Moscow: ASV, 2013. 480 p.
- Sokolova Yu.A. Epoksidnyye polimerbetony, modifitsirovannyye neftyanymi bitumami, kamennougol’noy i karbamidnoy smolami i aminoproizvodnymi soyedineniyami / pod. red. Yu.A. Sokolovoi, V.T. Yerofeyeva [Epoxy polymer concretes modified with petroleum bitumen, coal and urea resins and amino derivatives / under. ed. by V.T. Erofeev]. Moscow: Paleotype, 2008. 244 p. смолами и аминопроизводными соединениями / Под ред. Ю.А. Соко- ловой, В.Т. Ерофеева. М.: Палеотип, 2008. 244 с.
- Erofeev V., Tyuryakhin A., Tyuryakhina T. Flat space of values of volume module of grain composite with spherical fill-lem. International Journal of Civial Engineering and Technology (IJCIET). 2019. Vol. 10 (8), pp. 333–342.
- Ma P.C., Mo S.Y., Tang B.Z., Kim J.K. Dispersion, interfacial interaction and re-agglomeration of functionalized carbon nanotubes in epoxy composites. 2010. Carbon. Vol. 48. Iss. 6, pp. 1824–1834. doi: 10.1016/j.carbon.2010.01.028
- Rahmat M., Hubert P. Carbon nanotube-polymer interactions in nanocomposites: A review. Composites Science and Technology. 2011. Vol. 72. Iss. 1, pp. 72–84. doi: 10.1016/j.compscitech.2011.10.002
- Kathi J., Rhee K.Y., Lee J.H. Effect of chemical functionalization of multi-walled carbon nanotubes with 3-aminopropyltriethoxysilane on mechanical and morphological properties of epoxy nanocomposites. Composites. Part A. Applied Science and Manufacturing. 2009. Vol. 40. Iss. 6, pp. 800–809. doi: 10.1016/j.compositesa.2009.04.001
- Rafiee M., Rafiee J., Srivastava I. Fracture and fatigue in graphene nanocomposites. Nano. Micro. Small. 2010. Vol. 6. Iss. 2, pp. 179–183. https://doi.org/10.1002/smll.200901480
- Sun L., Gibson R.F., Gordaninejad F., Suhr J. Energy absorption capability of nanocomposites: a review. Composites Science and Technology. 2009. Vol. 69. Iss. 14, pp. 2392–2409. doi: 10.1016/j.compscitech.2009.06.020
- Tang L.Ch., Zhang H., Han J. Fracture mechanisms of epoxy filled with ozone functionalized multi-wall carbon nanotubes. Composites Science and Technology. 2011. Vol. 72, pp. 7–13. doi: 10.1016/j.compscitech.2011.07.016
- Ni Y., Chen L., Teng K., Shi J. Superior mechanical properties of epoxy composites reinforced by 3D interconnected graphene skeleton. ACS Applied Materials & Interfaces. 2015. Vol. 7. Iss. 21, pp. 11583–11591. doi: 10.1021/acsami.5b02552
- Rahman R., Haque A. Molecular modeling of crosslinkedgraphene-epoxy nanocomposites for characterization of elastic constants and interfacial properties. Engineering. Composites Part B: Engineering. 2013. Vol. 54, pp. 353–364. doi: 10.1016/J.COMPOSITESB.2013.05.034
- Qiao R., Brinson L.C. Simulation of interphase percolation and gradients in polymer nanocomposites. Composites Science and Technology. Composites Science and Technology. 2009. Vol. 69. Iss. 3–4, pp. 491–499. doi: 10.1016/j.compscitech. 2008.11.022
- Ayatollahi M.R., Shadlou S., Shokrieh M., Chitsazzadeh M. Effect of multi-walled carbon nanotube aspect ratio on mechanical and electrical properties of epoxy-based nanocomposites. Polymer Testing. 2011. Vol. 30. Iss. 5, pp. 548–556. doi: 10.1016/j.polymertesting.2011.04.008
- Hamming L., Qiao R., Messersmith P., Brinson L.C. Effects of dispersion and interfacial modification on the macroscale properties of TiO2 polymer-matrix nanocomposites. Composites Science and Techno- logy. 2009. Vol. 69, Iss. 11–12, pp. 1880–1886. doi: 10.1016/j.compscitech.2009.04.005
- Yang S., Yu S., Woomin K., Do-Suck H., Maenghyo C. Multiscale modeling of size-dependent elastic properties of carbon nanotube/polymer nanocomposites with interfacial imperfections. Polymer. 2012. Vol. 53. Iss. 2, pp. 623–6332012. doi: 10.1016/j.polymer.2011.11.052
- Erofeev V.T., Afonin V.V., El’chishheva T.F., Zotkina M.M., Erofeeva I.V. Using scanned images to assess salt formation on the surface of cementitious composites. Vestnik MSUCE. 2020. Vol. 15. No. 11, pp. 1523–1533. (In Russian). doi: 10.22227/1997-0935.2020.11.1523-1533
- Erofeev T., Likomaskina M., Afonin V., Likomaskin A., Tolmacheva V., Kotlyarskaya I. Microbiological resistance of sand-bitumen concrete. AlfaBuild. 2022. Vol. 25. Iss. 5. 2503. doi: 10.57728/ALF.25.3
- Maksimova I.N., Erofeeva I.V., Afonin V.V., Emelya- nov D.V. Assessing the quality of cement composites exposed to a temperature-aggressive environment using interpolation and correlation. Vestnik MSUCE. 2021. Vol. 16. Iss. 11, pp. 1473–1482. (In Russian). doi: 10.22227/1997-0935.2021.11.1473-1482
- Erofeeva I.V, Afonin V.V., Fedortsov V.A., Emelyanov D.V. Research of behavior of cement composites in conditions of high humidity and variable positive temperatures. IOP Conference Series Materials Science and Engineering. 2020. Vol. 972 (1). 012052. doi: 10.1088/1757-899X/972/1/012052
- Tarasyuk I.A., Kravchuk A.S. Narrowing of the Voigt-Reuss «Fork» in the theory of elastic, structurally inhomogeneous, on average, isotropic composite bodies without the use of variational principles. APRIORI. Series: Natural and technical sciences. 2014. No. 3, p. 8. (In Russian).
- Gumenyuk A.N., Polyanskikh I.S., Petrunin S.M., Shevchenko F.E., Pervushin G.N. Multifunctional layered composite material used in construction. Vestnik MSUCE. 2021. Vol. 16. No. 6, pp. 688–697. (In Russian). doi: 10.22227/1997-0935.2021.6.688-697
- Safarov A.R., Dorozhinsky V.B., Andreev V.I. Implementation of a numerical model of concrete CSCM for domestic classes of concrete. Vestnik MSUCE. 2023. Vol. 18. No. 4, pp. 545–555. (In Russian). doi: 10.22227/1997-0935.2023.4.545-555
- Urkhanova L.A., Buyantuev S.L., Urkhanova A.A., Lkhasaranov S.A., Ardashova G.R., Fediuk R.S. et al. Mechanical and electrical properties of concrete modified by carbon nanoparticles. Magazine of Civil Engineering. 2019. Vol. 8. No. 92, pp. 163–172. doi: 10.18720/MCE.92.14
- Yakovlev G., Vít Č., Polyanskikh I., Gordina A., Pudov I., Gumenyuk A., Smirnova O. The effect of complex modification on the impedance of cement matrices. Materials. 2021. Vol. 14. Iss. 3. 557. doi: 10.3390/ma14030557
- Lam N.D.T., Samchenko S.V., Lam T.V., Shvetso- va V.A. Optimization of the proportions of a composite binder containing multicomponent additives. Vestnik MSUCE. 2023. Iss. 18. No. 3, pp. 427–437. (In Russian). doi: 10.22227/1997-0935.2023.3.427-437
- Omidi M., Milani A.S., Seethaler R., Arasteh R. Prediction of the mechanical characteristics of mul- ti-walled carbon nanotube/epoxy composites using a new form of the rule of mixtures. Carbon. 2010. Vol. 48. Iss. 11, pp. 3218–3228. doi: 10.1016/j.carbon.2010.05.007
- Lazarev A.V., Kaznacheev S.V., Erofeev V.T., Bredikhin V.V., Khudyakov V.A. Optimization of compositions of filled epoxy composites in terms of strength indicators. Izvestiya of the Southwestern State University. Series: Equipment and technology. 2012. No. 2–3, pp. 235–239. (In Russian).
- Erofeev V.T., Volgina E.V., Kaznacheev S.V., Kreto- va V.M. Research on the strength of vinylester composites. Izvestiya of the Southwestern State University. Series: Equipment and technology. 2013. No. 4, pp. 81–88. (In Russian).
- Bobryshev A.N., Erofeev V.T., Kozomazov V.N. Fizika i sinergetika dispersno-neuporyadochennykh kondensirovannykh kompozitnykh sistem [Physics and synergetics of dispersed disordered condensed composite systems]. St. Petersburg: Nauka. 2012. 473 p.
- Gibbons J.D. Nonparametric Statistical Inference. New York. Basel: CRC Press. 2010. 652 p.
- Kim I., Balakrishnan S., Wasserman L. Robust multivariate nonparametric tests via projection averaging. Annals of Statistics. 2020. Vol. 48. Iss. 6, pp. 3417–3441. https://doi.org/10.48550/arXiv.1803.00715
- Pan W., Tian Y., Wang X., Zhang H. Ball divergence: nonparametric two sample test. Annals of Statistics. 2018. Vol. 46. Iss. 3, pp. 1109–1137. doi: 10.1214/17-AOS1579
- Kotlyar M., Fuhrman S., Ableson A., Somogyi R. Spearman correlation identifies statistically significant gene expression clusters in spinal cord develop- ment and injury. Neurochemical Research. 2004, pp. 1133–1140. doi: 10.1023/a:1020969208033
- Kobzar A.I. Prikladnaya matematicheskaya statistika. Dlya inzhenerov i nauchnykh rabotnikov [Applied mathematical statistics. For engineers and scientists]. Moscow: Fizmatlit. 2006. 816 p.
Supplementary files
