Reactions of fluorine atoms with benzene, fluorobenzene and chlorobenzene

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

Benzene and its derivatives are extremely important substances in modern chemical technologies. However, emissions of these substances have an extremely negative impact on the atmosphere and ecology. Benzene is a substance of the second class of danger and its effect on the human body is fraught with serious consequences. In the event of man-made disasters, an urgent task is to convert benzene into less toxic substances. In this work, using a low-pressure flow reactor, the kinetic patterns of the reactions of atomic fluorine with benzene, fluorobenzene, and chlorobenzene at a temperature T = 293 K and a pressure of 0.8–1.3 Torr were established. The concentrations of reagents and products were controlled by molecular beam mass spectrometry. To determine reaction rate constants, the method of competing reactions was used. The reaction of fluorine atoms with cyclohexane was chosen as a competitor. As a result of the analysis using experimental and literature data, the following values of the rate constants of the studied reactions were obtained.

全文:

受限制的访问

作者简介

E. Vasiliev

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: vasiliev@chph.ras.ru
俄罗斯联邦, Moscow

I. Morozov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: vasiliev@chph.ras.ru
俄罗斯联邦, Moscow

N. Volkov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: vasiliev@chph.ras.ru
俄罗斯联邦, Moscow

S. Savilov

Lomonosov Moscow State University

Email: vasiliev@chph.ras.ru
俄罗斯联邦, Moscow

O. Morozova

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: vasiliev@chph.ras.ru
俄罗斯联邦, Moscow

N. Butkovskaya

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: vasiliev@chph.ras.ru
俄罗斯联邦, Moscow

P. Khomyakova

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences; Mendeleev University of Chemical Technology of Russia

Email: vasiliev@chph.ras.ru
俄罗斯联邦, Moscow; Moscow

参考

  1. D. J. Smith, D. W. Setser, K. C. Kim, and D. J. Bogan, J. Phys. Chem. 81, 898 (1977). https://doi.org/10.1021/j100524a019
  2. J. Ebrecht, W. Hack, and H. G. Wagner, Ber. Bunsenges. Phys. Chem. 93, 619 (1989). https://doi.org/10.1002/bbpc.19890930520
  3. F. Markert and P. Pagsberg, Chem. Phys. Lett. 209, 445 (1993). https://doi.org/10.1016/0009-2614(93)80115-6
  4. E. S. Vasiliev, N. D. Volkov, G. V. Karpov, et al., Russ. J. Phys. Chem. A 94, 2004 (2020). https://doi.org/10.1134/S0036024420100295
  5. E. S. Vasiliev, N. D. Volkov, G. V. Karpov, et al., Russ. J. Phys. Chem. B 15, 789 (2021); https://doi.org/10.1134/S1990793121050213
  6. S. O. Adamson, D. D. Kharlampidi, A. S. Shtyrkova, et al., Atoms 11, 132 (2023). https://doi.org/10.3390/atoms11100132
  7. R. Atkinson, D. L. Baulch, R. A. Cox, et al., Atmos. Chem. Phys. 6, 3625 (2006). https://doi.org/10.5194/acp-6-3625-2006
  8. E. S. Vasiliev, G. V. Karpov, D. K. Shartava, et al., Russ. J. Phys. Chem. B 16, 388 (2022). https://doi.org/10.1134/S1990793122030113
  9. I. I. Morozov, E. S. Vasiliev, N. I. Butkovskaya, et al., Russ. J. Phys. Chem. B 17, 1091 (2023). https://doi.org/10.1134/S1990793123050251
  10. R. Pearson, J. Cowles, G. Hermann, D. Gregg, and J. Creighton, IEEE J. Quantum Electron. 9, 879 (1973). https://doi.org/10.1109/JQE.1973.1077761
  11. R. G. Manning, E. R. Grant, J. C. Merrill, N. J. Parks, and J. W. Root, Int. J. Chem. Kinet. 7, 39 (1975). https://doi.org/10.1002/kin.550070106
  12. NIST Chemistry WebBook. https://webbook.nist.gov/chemistry/
  13. P. Heinemann-Fiedler, K. Hoyermann, and G. Rohde, Ber. Bunsenges. Phys. Chem. 94, 1400 (1990). https://doi.org/10.1002/bbpc.199000042
  14. E. S. Vasiliev, I. I. Morozov, and G. V. Karpov, Int. J. Chem. Kinet. 51, 909 (2019). https://doi.org/10.1002/kin.21319
  15. R. Atkinson, D. L. Baulch, R. A. Cox, et al., Atmos. Chem. Phys. 7, 981 (2007). https://doi.org/10.5194/acp-7-981-2007
  16. E. S. Vasiliev, I. I. Morozov, W. Hack, K.-H. Hoyermann, and M. Hold, Kinet. Catal. 47, 834 (2006). https://doi.org/10.1134/S0023158406060048
  17. S. O. Adamson, D. D. Kharlampidi, A. S. Shtyrkova, et al., Russ. J. Phys. Chem. B 18, 627 (2024). https://doi.org/10.1134/S1990793124700192
  18. I. I. Morozov, E. S. Vasiliev, N. D. Volkov, et al., Russ. J. Phys. Chem. B 16, 877 (2022). https://doi.org/10.1134/S1990793122050220
  19. Il. S. Golyak, D. R. Anfimov, I. B. Vintaykin, et al., Russ. J. Phys. Chem. B 17, 320 (2023). https://doi.org/10.1134/S1990793123020264

补充文件

附件文件
动作
1. JATS XML
下载
2. Fig. 1. Dependences of the depth of conversion of the reagents of the studied reactions with atomic fluorine on the depth of conversion of cyclohexane in reaction (23): a – for benzene in reaction (1); b – for fluorobenzene in reaction (21); c – for chlorobenzene in reaction (22).

下载 (53KB)
索引源数据
3. Fig. 2. Mass spectra of fluorobenzene and difluorobenzenes according to [12], obtained as a result of electron impact ionization at an electron energy of 70 eV. The dashed lines indicate the locations of the molecular peaks of fluorobenzene (M(1)+, m/z = 96) and cyclohexane (M(2)+, m/z = 84).

下载 (108KB)
索引源数据
4. Fig. 3. Mass spectra of chlorobenzene and chlorofluorobenzenes according to [12], obtained as a result of electron impact ionization at an electron energy of 70 eV. The dashed lines indicate the locations of the molecular peaks of chlorobenzene (M(1)+, m/z = 112) and cyclohexane (M(2)+, m/z = 84).

下载 (117KB)
索引源数据
5. Fig. 4. Mass spectra of C6H5Cl, C6H6 and C6H5F, normalized for C6H5Cl and C6H6 to 100% by the most intense molecular peaks of the spectra at m/z = 112 and m/z = 78, respectively. The dashed lines show the locations of the molecular peaks of chlorobenzene (M(1)+, m/z = 112) and benzene (M(2)+, m/z = 78).

下载 (78KB)
索引源数据

版权所有 © Russian Academy of Sciences, 2024