Methyl-Substituted Derivatives of Furazanoazepines: Synthesis, Structure, Enthalpy of Formation, and Ballistic Efficiency

D. B. Lempert; Лемперт Д. Б.; E. L. Ignatieva; Игнатьева Е. Л.; A. I. Stepanov; Степанов А. И.; D. V. Dashko; Дашко Д. В.; A. I. Kazakov; Казаков А. И.; A. V. Nabatova; Набатова А. В.; G. V. Shilov; Шилов Г. В.; D. V. Korchagin; Корчагин Д. В.; S. M. Aldoshin; Алдошин С. М.

doi:10.31857/S0207401X23090066

Methyl-Substituted Derivatives of Furazanoazepines: Synthesis, Structure, Enthalpy of Formation, and Ballistic Efficiency

作者: Lempert D.B.¹, Ignatieva E.L.¹, Stepanov A.I.², Dashko D.V.², Kazakov A.I.¹, Nabatova A.V.¹, Shilov G.V.¹, Korchagin D.V.¹, Aldoshin S.M.¹
隶属关系:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
2. Special Design and Technological Bureau “Technolog”
期: 卷 42, 编号 9 (2023)
页面: 20-29
栏目: Combustion, explosion and shock waves
URL: https://cardiosomatics.orscience.ru/0207-401X/article/view/674826
DOI: https://doi.org/10.31857/S0207401X23090066
EDN: https://elibrary.ru/TTDDMT
ID: 674826

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详细

Energy-intensive compounds AzCH3, 7-methyl-7Н-trifurazano[3,4-b:3′,4′-f:3″,4″-d]azepine, and Az(O)CH3, 7-methyl-7Н-difurazano[ 3,4-b:3′,4′-f]furoxano[3″,4″-d]azepine, are extensively studied as potential dispersants in gas-generating fuels. The main parameters of the crystal lattice are determined by X‑ray diffraction analysis and experimental data on the heats of combustion and enthalpies of the formation of AzCH3 and Az(O)CH3 are obtained. A thermodynamic analysis of the effectiveness of these compounds in gas-generating fuels is carried out. It is shown that AzCH3 and Az(O)CH3 are very effective as potential dispersants of solid fuels for gas generator engines.

关键词

methyl derivatives, azepines, furazans, X-ray diffraction analysis, enthalpy of formation, ballistic efficiency

参考

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