Miniaturized methods for isolation and preconcentration: micro-solid-phase extraction and solid-phase microextraction of organic compounds. A review of reviews

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

Miniaturized methods for sorptive isolation and preconcentration of organic compounds include micro-solid-phase extraction (μ-SPE) and solid-phase microextraction (SPME). These methods are characterized by reduced amounts of sorbents, analyzed samples, and organic solvents, high preconcentration factors, and the integration of preconcentration and sample introduction into a single device. Since the emergence of μ-SPE (1989) and SPME (1990), numerous variants of these methods have been developed, differing in sample preparation techniques, the nature of the sorbents used, and their integration with subsequent determination methods. The popularity of these methods is evidenced by the large number of reviews summarized in this publication.

Авторлар туралы

S. Dmitrienko

Department of Chemistry, Lomonosov Moscow State University

Email: nikatolm@mail.ru
Moscow, Russia

V. Apyari

Department of Chemistry, Lomonosov Moscow State University

Email: nikatolm@mail.ru
Moscow, Russia

V. Tolmacheva

Department of Chemistry, Lomonosov Moscow State University

Email: nikatolm@mail.ru
Moscow, Russia

M. Matyash

Department of Chemistry, Lomonosov Moscow State University

Email: nikatolm@mail.ru
Moscow, Russia

A. Furletov

Department of Chemistry, Lomonosov Moscow State University

Email: nikatolm@mail.ru
Moscow, Russia

Yu. Zolotov

Department of Chemistry, Lomonosov Moscow State University

Хат алмасуға жауапты Автор.
Email: nikatolm@mail.ru
Moscow, Russia

Әдебиет тізімі

  1. López-Lorente A.I., Pena-Pereira F., Pedersen-Bjergaard S., Zuin V.G., Ozkan S.A., Psillakis E. The ten principles of green sample preparation // Trends Anal. Chem. 2022. V. 148. Article 116530.
  2. Pena-Pereira F., Lavilla I., Bendicho C. Greening sample preparation: an overview of cutting-edge contributions // Curr. Opin. Green Sustain. Chem. 2021. V. 30. Article 100481.
  3. Câmara J.S., Perestrelo R., Berenguer C.V., Andrade C.F.P., Gomes T.M., Olayanju B., Kabir A., Rocha C. M.R., Teixeira J.A., Pereira J.A.M. Green extraction techniques as advanced sample preparation approaches in biological, food, and environmental matrices. A review // Molecules. 2022. V. 27. Article 2953.
  4. Esteve-Turrillas F.A., Garrigues S., de la Guardia M. Green extraction techniques in green analytical chemistry: A 2019–2023 up-date // Trends Anal. Chem. 2024. V. 170. Article 117464.
  5. Cheriyan B.V., Karunakar K.K, Anandakumar R., Murugathirumal A., Kumar A.S. Eco-friendly extraction technologies: A comprehensive review of modern green analytical methods // Sustain. Chem. Clim. Act. 2025. V. 6. Article 100054.
  6. Бессонова Е.А., Карпицкий Д.А., Карцова Л.А. Современные подходы к извлечению и концентрированию биологически активных веществ из растительных объектов с применением методов микроэкстракции для их хромато-массспектрометрического определения // Журн. аналит. химии. 2023. Т. 78. № 10. С. 883. (Bessonova E.A., Karpitskii D.A., Kartsova L.A. Modern approaches to the extraction and preconcentration of biologically active compounds from plant samples by microextraction methods for their determination by chromatography–mass spectrometry // J. Anal. Chem. 2023. V. 78. № 10. P. 1295.)
  7. Hansen F.A.A., Pedersen-Bjergaard S. Emerging extraction strategies in analytical chemistry // Anal. Chem. 2020. V. 92. P. 2.
  8. Kokosa J.M., Przyjazny A. Green microextraction methodologies for sample preparations // Green Anal. Chem. 2022. V. 3 (Part 1). Article 100023.
  9. Carasek E., Scur R., Bernardi G. High-throughput analytical methods employing microextraction techniques: Towards fast analyses lasting a few seconds // Adv. Sample Prep. 2023. V. 8. Article 100095.
  10. Soares da Silva Burato J., Vargas Medina D.A., de Toffoli A. L., Maciel E. V. S., Mauro Lanças F. Recent advances and trends in miniaturized sample preparation techniques // J. Sep. Sci. 2020. V. 43. P. 202.
  11. Azorín C., Benedé J.L., Chisvert A. Ultramicroextraction as a miniaturization of the already miniaturized. A step toward nanoextraction and beyond // J. Sep. Sci. 2023. V. 46. Article 2300223.
  12. Peris-Pastor G., Azorín C., Grau J., Benedé J.L., Chisvert A. Miniaturization as a smart strategy to achieve greener sample preparation approaches: A view through greenness assessment // Trends Anal. Chem. 2024. V. 170. Article 117434.
  13. Tintrop L.K., Salemi A., Jochmann M.A., Engewald W.R., Schmidt T.C. Improving greenness and sustainability of standard analytical methods by microextraction techniques: A critical review // Anal Chim Acta. 2023. V. 1271. Article 341468.
  14. Vakh C., Tobiszewski M. Greenness assessment of analytical methods used for antibiotic residues determination in food samples // Trends Anal. Chem. 2023. V. 166. Article 117162.
  15. Шишов А.Ю., Моходоева О.Б. Индексы экологичности в аналитической химии // Журн. аналит. химии. 2024. Т. 79. № 5 С. 425. (Shishov A.Y., Mokhodoyeva O.B. Green chemistry metrics in analytical chemistry // J. Anal. Chem. 2024. V. 79. № 5. P. 487.)
  16. Ma X., Wang L.Y., He Q., Sun Q., Yin D., Zhang Y. A review on recent developments and applications of green sorbents-based solid phase extraction techniques // Adv. Sample Prep. 2023. V. 6. Article 100065.
  17. Saura-Cayuela M., Lara-Torres S., Pacheco-Fernandez I., Trujillo-Rodríguez M.J., Ayala J.H, Pino V. Green materials for greener food sample preparation: A review // Green Anal. Chem. 2023. V. 4. Article 100053.
  18. Marć M., Jatkowska N., Guardia M. Molecularly imprinted polymers based on deep eutectic solvents as a greenest material for selective extraction of emerging contaminants from complex samples // Trends Anal. Chem. 2024. V. 178. Article 117837.
  19. Santos H., Martins R.O., Soares D.A., Chaves A.R. Molecularly imprinted polymers for miniaturized sample preparation techniques: strategies for chromatographic and mass spectrometry methods // Anal. Methods. 2020. V. 12. № 7. P. 894.
  20. Oliveira R., Ricardo M., Andréa A.B., Machado L.S., Junior A.C.B., Maciel L.Í.L., Alves de Aguiar D.V., Neto F.O.S., Oliveira J.V.A., Simas R.C., Chaves R. Greener molecularly imprinted polymers: Strategies and applications in separation and mass spectrometry methods // Trends Anal. Chem. 2023. V. 168. Article 117285.
  21. Tabani H., Alexovič M., Sabo J., Payán M.R. An overview on the recent applications of agarose as a green biopolymer in micro-extraction-based sample preparation techniques // Talanta. 2020. V. 224. Article 121892.
  22. Płotka-Wasylka J., Chabowska A., Pantanit S., Bunkoed O., Fares M.Y., Sajid M., Lambropoulou D., Kurowska-Susdorf A., Jatkowska N. Natural/bio-based sorbents as greener extractive materials for endocrine disrupting compounds in samples of different matrix composition // Trends Anal. Chem. 2024. V. 176. Article 117773.
  23. Martins R.O., Cardoso A.T., Borsatto J.V., Lanças F.M. Advances in green carbon-based biosorbents: From conventional to miniaturized sample preparation strategies // Talanta. 2025. V. 283. Article 127171.
  24. Zhang Y., Chen M., Li L., Lv Y., Ma Q. Recent advances in microextraction techniques using sustainable green solvents for mass spectrometry analysis // Trends Anal. Chem. 2024. V. 170. Article 117412.
  25. Yavir K., Konieczna K., Marcinkowski Ł., Kloskowski A. Ionic liquids in the microextraction techniques: The influence of ILs structure and properties // Trends Anal. Chem. 2020. V. 130. Article 115994.
  26. Marcinkowska R., Konieczna K., Marcinkowski Ł., Namieśnik J., Kloskowski A. Application of ionic liquids in microextraction techniques: Current trends and future perspectives // Trends Anal. Chem. 2019. V. 119. Article 115614.
  27. Carasek E., Bernardi G., Morelli D., Merib J. Sustainable green solvents for microextraction techniques: recent developments and applications // J. Chromatogr. A. 2021. V. 1640. Article 461944.
  28. Hosseininezhad B., Nemati M., Farajzadeh M.A., Khosrowshahi E.M., Mogaddam M.R.A. Deep eutectic solvent applications in sample preparation of different analytes before gas and liquid chromatography instruments coupled with mass spectrometry and tandem mass spectrometry // Trends Anal. Chem. 2023. V. 169. Article 117346.
  29. Khan W.A., Varanusupakul P., Haq H.U., Arain M.B., Marchel M., Boczkaj G. Diverse roles, advantages and importance of deep eutectic solvents application in solid and liquid-phase microextraction techniques – A review // Sep. Purif. Technol. 2025. V. 358. Article 130362.
  30. Alshana U., Hassan M., Al-Nidawi M., Yilmaz E., Soylak M. Switchable-hydrophilicity solvent liquid-liquid microextraction // Trends Anal. Chem. 2020. V. 131. Article 116025.
  31. Kannouma R.E., Hammad M.A., Kamal A.H., Mansour F.R. Miniaturization of liquid-liquid extraction; the barriers and the enablers // Microchem. J. 2022. V. 182. Article 107863.
  32. Kailasa S.K., Koduru J.R., Park T.J., Singhal R.K., Wu H.-F. Applications of single-drop microextraction in analytical chemistry: A review // Trends Environ. Anal. Chem. 2021. V. 29. Article e00113.
  33. Дмитриенко С.Г., Апяри В.В., Толмачева В.В., Горбунова М.В. Жидкостная экстракция органических соединений в каплю экстрагента. Обзор обзоров // Журн. аналит. химии. 2021. Т. 76. № 8. С. 675. (Dmitrienko S.G., Apyari V.V., Tolmacheva V.V., Gorbunova M.V. Liquid–liquid extraction of organic compounds into a single drop of the extractant: Overview of reviews // J. Anal. Chem. 2021. V. 76. № 8. P. 907.)
  34. Mansour F.R., Bedair A., Hamed M., Magdy G., Ali I., Locatelli M. Applications of (natural) deep eutectic solvents in liquid phase microextraction: A review // Microchem. J. 2024. V. 198. Article 110178.
  35. Дмитриенко С.Г., Апяри В.В., Толмачева В.В., Горбунова М.В. Дисперсионная жидкостно-жидкостная микроэкстракция органических соединений. Обзор обзоров // Журн. аналит. химии. 2020. Т. 75. № 10. С. 867. (Dmitrienko S.G., Apyari V.V., Tolmacheva V.V., Gorbunova M.V. Dispersive liquid–liquid microextraction of organic compounds: an overview of reviews // J. Anal. Chem. 2020. V. 75. № 10. P. 1237.)
  36. Sajid M. Dispersive liquid-liquid microextraction: Evolution in design, application areas, and green aspects // Trends Anal. Chem. 2022. V. 152. Article 116636.
  37. Faraji H. Advancements in overcoming challenges in dispersive liquid-liquid microextraction: An overview of advanced strategies // Trends Anal. Chem. 2024. V. 170. Article 117429.
  38. Дмитриенко С.Г., Апяри В.В., Горбунова М.В., Толмачева В.В., Золотов Ю.А. Гомогенная жидкостная микроэкстракция органических соединений // Журн. аналит. химии. 2020. Т. 75. № 11. С. 963. (Dmitrienko S.G., Apyari V.V., Gorbunova M.V., Tolmacheva V.V., Zolotov Yu A. Homogeneous liquid–liquid microextraction of organic compounds // J. Anal. Chem. 2020. V. 75. № 11. P. 1371.)
  39. Ramezani A.M., Ahmadi R., Yamini Y. Homogeneous liquid-liquid microextraction based on deep eutectic solvents // Trends Anal. Chem. 2022. V. 149. Article 116566.
  40. Дмитриенко С.Г., Апяри В.В., Толмачева В.В., Горбунова М.В., Фурлетов А.А. Дисперсионная и магнитная твердофазная экстракция органических соединений. Обзор обзоров // Журн. аналит. химии. 2024. Т. 79. № 2. С. 99. (Dmitrienko S.G., Apyari V.V., Tolmacheva V.V., Gorbunova M.V., Furletov A.A. Dispersive and magnetic solid-phase extraction of organic compounds: Review of reviews // J. Anal. Chem. 2024. V. 79. № 2. P. 105.)
  41. Hashim N.M., Husani N.I.M., Wardani N.I., Alahmad W., Shishov A., Madurani K.A., Liao P.-C., Yahaya N., Zain N.N.M. Advancements in effervescent-assisted dispersive micro-solid phase extraction for the analysis of emerging pollutants // Anal. Chim. Acta. 2024. V. 1325. Article 342891.
  42. Vega-Morales T., Sosa-Ferrera Z., Santana-Rodríguez J.J., Montesdeoca-Esponda S. Magnetic-based microextraction systems for the determination of emerging contaminants in environmental liquid samples // Trends Anal. Chem. 2025. V. 183. Article 118116.
  43. Дмитриенко С.Г., Апяри В.В., Толмачева В.В., Горбунова М.В., Фурлетов А.А., Цизин Г.И., Золотов Ю.А. Методы выделения органических соединений из твердых образцов. 2. Экстракция в суб- и сверхкритических условиях. Матричная твердофазная дисперсия. Метод QUECHERS. Обзор обзоров // Журн. аналит. химии. 2024. Т. 79. № 9. С. 935. (Dmitrienko S.G., Apyari V.V., Tolmacheva V.V., Gorbunova M.V., Furletov A.A., Tsizin G.I., Zolotov Yu.A. Methods for extraction of organic compounds from solid samples: 2. Sub- and supercritical extraction. Matrix solid-phase dispersion. QuEChERS method. Review of reviews // J. Anal. Chem. 2024. V. 79. № 9. P. 1167.)
  44. Ramos L. Current trends in the determination of organic compounds in foodstuffs using matrix solid phase dispersion // Trends Anal. Chem. 2024. V. 172. Article 11760.
  45. Зайцев В.Н., Зуй М.Ф. Твердофазное микроэкстракционное концентрирование // Журн. аналит. химии. 2014. Т. 69. № 8. С. 787. (Zaitsev V.N., Zui M.F. Preconcentration by solid-phase microextraction // J. Anal. Chem. 2014. V. 69. № 8. P. 715.)
  46. Федотов П.С., Малофеева Г.И., Савонина Е.Ю., Спиваков Б.Я. Твердофазная экстракция органических веществ: нетрадиционные методы и подходы // Журн. аналит. химии. 2019. Т. 74. С. 163. (Fedotov P.S., Malofeeva G.I., Savonina E.Yu., Spivakov B.Ya. Solid-phase extraction of organic substances: Unconventional methods and approaches // J. Anal. Chem. 2019. V. 74. № 3. P. 205.)
  47. Badawy M.E.I., El-Nouby M.A.M., Kimani P.K., Lim L.W., Rabea E.I. A review of the modern principles and applications of solid-phase extraction techniques in chromatographic analysis // Anal. Sci. 2022. V. 38. P.1457.
  48. Sajid M., Nazal K.M., Rutkowska M., Szczepańska N., Namieśnik J., Płotka-Wasylka J. Solid phase microextraction: Apparatus, sorbent materials, and application // Crit. Rev. Anal. Chem. 2018. V. 49. P. 1.
  49. Trujillo-Rodríguez M.J., Pacheco-Fernández I., Taima-Mancera I., Díaz J.H.A., Pino V. Evolution and current advances in sorbent-based microextraction configurations // J Chromatogr A. 2020. V. 1634. Article 461670.
  50. Marrubini G., Dugheri S., Cappelli G., Arcangeli G., Mucci N., Appelblad P., Melzi C., Speltini A. Experimental designs for solid-phase microextraction method development in bioanalysis: A review // Anal. Chim. Acta. 2020. V. 1119. P. 77.
  51. Salve S., Bahiram Y., Jadhav A., Rathod R., Tekade R.K. Nanoplatform-integrated miniaturized solid-phase extraction techniques: A critical review // Crit. Rev. Anal. Chem. 2023. V. 53. P. 46.
  52. Arthur C.L., Pawliszyn J. Solid-phase microextraction with thermal desorption using fused-silica optical fibers // Anal. Chem. 1990. V. 62. P. 2145.
  53. Torabi E., Abdar A., Lotfian N., Bazargan M., Simms C., Moussawi M.A., Amiri A., Mirzaei M., Parac-Vogt T.N. Advanced materials in sorbent-based analytical sample preparation // Coord. Chem. Rev. 2024. V. 506. Article 215680.
  54. Medina D.A.V., Cardoso A.T., Maciel E.V.S., Lanças F.M. Current materials for miniaturized sample preparation: Recent advances and future trends // Trends Anal. Chem. 2023. V. 165. Article 117120.
  55. Castañeda F.N., Prince D.L., Peirano S.R., Giovannoni S., Echevarría R.N., Keunchkarian S., Reta M. New sorbents for sample pretreatment: Development and applications // Trends Anal. Chem. 2024. V. 180. Article 117924.
  56. Jiang Q., Zhang S., Sun M. Recent advances on graphene and graphene oxide as extraction materials in solid-phase (micro)extraction // Trends Anal. Chem. 2023. V. 168. Article 117283.
  57. Cardoso A.T., Martins R. O., Lança F.M. Advances and applications of hybrid graphene-based materials as sorbents for solid phase microextraction techniques // Molecules. 2024. V. 29. Article 3661.
  58. Ghorbani M., Keshavarzi M., Pakseresht M., Mohammadi P., Abad M.O.K., Mehraban A. Advancements, applications, and prospects of metal-organic frameworks and their derivatives as distinct sorbents in exhaustive and non-exhaustive extraction strategies // Microchem. J. 2024. V. 198. Article 110158.
  59. Khataei M. M., Yamini Y., Shamsayei M. Applications of porous frameworks in solid-phase microextraction // J. Sep. Sci. 2021. V. 44. P. 1231.
  60. Guo W., Tao H., Tao H., Shuai Q., Huang L. Recent progress of covalent organic frameworks as attractive materials for solid-phase microextraction: A review // Anal. Chim. Acta. 2024. V. 1287. Article 341953.
  61. Bunkoed O., Orachorn N., Jullakan S., Nurerk P. Composite solid phase adsorbents: Carbon-based and framework-based materials for micro-extraction of trace organic compounds // Trends Anal. Chem. 2024. V. 177. Article 117808.
  62. Sereshti H., Duman O., Tunç S., Nouri N., Khorram P. Nanosorbent-based solid phase microextraction techniques for the monitoring of emerging organic contaminants in water and wastewater samples // Microchim. Acta. 2020. V. 187. P. 541.
  63. Yahaya N., Zain N.N.M., Mohamed A.H., Kamaruzaman S., Miskam M., Jain R., Raoov M., Abdullah W.N.W. Nanosorbents in solid-phase extraction techniques for bioanalysis: A review // Microchem. J. 2024. V. 207. Article 112170.
  64. Martins R.O., Junior A.C.B., Brito C.C.S.M., Rocha Y.A., Chaves A.R. Molecularly imprinted polymers in solid-phase microextraction: Enhancing the analysis of pharmaceutical compounds across diverse sample matrices // J. Pharm. Biomed. Anal. Open. 2024. V. 4. Article 100037.
  65. Martins R.O., Junior A.C.B., Machado L.S., Chaves A.R. Integration of miniaturized sample preparation and molecularly imprinted polymers in food analysis // Green Anal. Chem. 2024. V. 10. Article 100134.
  66. Pacheco-Fernández I., Allgaier-Díaz D.W., Mastellone G., Cagliero C., Díaz D.D., Pino V. Biopolymers in sorbent-based microextraction methods // Trends Anal. Chem. 2020. V. 125. Article 115839.
  67. Werner J., Zgoła-Grześkowiak A., Grześkowiak T., Frankowski R. Biopolymers-based sorbents as a future green direction for solid phase (micro)extraction techniques // Trends Anal. Chem. 2024. V. 173. Article 117659.
  68. Carasek E., Mor´es L., Cunha N., Branco G.L., Dias A.N. Natural deep eutectic solvents and natural solid biosorbents in microextraction techniques of organic compounds based on chromatographic techniques: A critical review // Adv. Sample Prep. 2024. V. 12. Article 100139.
  69. Jatkowska N. Alginate-based sorbents in miniaturized solid phase extraction techniques – Step towards greenness sample preparation // Trends Anal. Chem. 2024. V. 180. Article 117893.
  70. Czyż E., Švec F., Šatínský D. Recent advances in application of nanofibers as extraction sorbents in environmental analysis // Trends Anal. Chem. 2024. V. 180. Article 117970.
  71. Sowa I., Wójciak M., Tyszczuk-Rotko K., Klepka T., Dresler S. Polyaniline and polyaniline-based materials as sorbents in solid-phase extraction // Materials. 2022. V. 15. Article 8881.
  72. Makoś-Chełstowska P., Gębicki J. Sorbents modified by deep eutectic solvents in microextraction techniques // Trends Anal. Chem. 2024. V. 172. Article 117577.
  73. Pena-Pereira F., Bendicho C., Pavlović D.M., Martín-Esteban A., Díaz-Álvarez M., Pan Y., Cooper J., Yang Z., Safarik I., Pospiskova K., Segundo M.A., Psillakis E. Miniaturized analytical methods for determination of environmental contaminants of emerging concern – A review // Anal. Chim. Acta 2021. V. 1158. Article 238108.
  74. Płotka-Wasylka J., Jatkowska N., Paszkiewicz M., Caban M., Fares M.Y., Dogan A., Garrigues S., Manousi N., Kalogiouri N., Nowak P.M., Samanidou V.F., Guardia M. Miniaturized solid phase extraction techniques for different kind of pollutants analysis: state of the art and future perspectives PART 1 // Trends Anal. Chem. 2023. V.162. Article 117034.
  75. Płotka-Wasylka J., Jatkowska N., Paszkiewicz M., Caban M., Fares M.Y., Dogan A., Garrigues S., Manousi N., Kalogiouri N., Nowak P.M., Samanidou V.F., Guardia M. Miniaturized solid phase extraction techniques for different kind of pollutants analysis: State of the art and future perspectives PART 2 // Trends Anal. Chem. 2023. V.165. Article 117140.
  76. Rodriguez-Saldana V., Castro-Garcia, C., Rodriguez-Maese R., Leal-Quezada L.O. Advances in the extraction methods for the environmental analysis of non- steroidal anti-inflammatory drugs (NSAIDs) // Trends Anal. Chem. 2023. V.169. Article 117409.
  77. Wang Q., Zhang Y., Zhou Y., Chen F., Feng X. Recent advances in microextraction techniques for sensitive determination of synthetic musks in complex samples // Trends Environ. Anal. Chem. 2024. V. 44. Article e00241.
  78. Casado N., Gañán J., Morante-Zarcero S., Sierra I. New advanced materials and sorbent-based microextraction techniques as strategies in sample preparation to improve the determination of natural toxins in food samples // Molecules. 2020. V. 25. P. 702.
  79. Jagirani M.S., Soylak M. Review: microextraction technique based new trends in food analysis // Crit. Rev. Anal. Chem. 2022. V. 52. P. 968.
  80. De Cesaris M.G., Antonelli L., Lucci E., Felli N., Bosco C.D., Gentili A. Current trends to green food sample preparation. A review // J. Chromatogr. Open. 2024. V. 6. Article 100170.
  81. Jin H.-F., Shi Y., Cao J. Recent advances and applications of novel advanced materials in solid-phase microextraction for natural products // Trends Anal. Chem. 2024. V. 180. Article 117858.
  82. Jalili V., Barkhordari A., Ghiasvand A. Bioanalytical applications of microextraction techniques: A review of reviews // Chromatographia. 2020. V. 83. P. 567.
  83. Jiménez-Skrzypek G., Ortega-Zamora C., González-Sálamo J., Hernández-Borges J. Miniaturized green sample preparation approaches for pharmaceutical analysis // J. Pharm. Biomed. Anal. 2022. V. 207. Article 114405.
  84. Soares S., Rosado T., Barroso, M., Gallardo E. Solid phase-based microextraction techniques in therapeutic drug monitoring // Pharmaceutics. 2023. V. 15. Article 1055.
  85. Ingle R.G., Zeng S., Jiang H., Fang W.-J. Current developments of bioanalytical sample preparation techniques in pharmaceuticals // J. Pharm. Anal. 2022. V. 12. P. 517.
  86. Gao Y., Sheng K., Bao T., Wang S. Recent applications of organic molecule-based framework porous materials in solid-phase microextraction for pharmaceutical analysis // J. Pharm. Biomed. Anal. 2022. V. 221. Article 115040.
  87. Nisyriou S., Zacharis C.K. Microextraction-based techniques for the determination of beta-blockers in biological fluids: A review // Separations. 2025. V. 12. P. 14.
  88. Al-Hammashi F., Deiminiat B., Rounaghi G.H. Development of solid-phase microextraction methods for determination of non-steroidal anti-inflammatory drugs // Microchem. J. 2025. V. 208 Article 112340.
  89. Ahmad S.M., Gonçalves O.C., Oliveira M N., Neng N. R., Nogueira J.M.F. Application of microextraction-based techniques for screening-controlled drugs in forensic context – A review // Molecules. 2021. V. 26. Article 2168.
  90. Rosado T., Barroso M., Vieira D.N., Gallardo E. Trends in microextraction approaches for handling human hair extracts – A review // Anal. Chim. Acta. 2021. V. 1185. Article 338792.
  91. Jain R., Yahaya N., Mohamed A.H., Kabir A., Chandrawanshi L.P., Elrahman M.A., Ghoneim M.M., Bakkannavar S.M. The role of emerging sample preparation methods in postmortem toxicology: Green and sustainable approaches // Trends Anal. Chem. 2023. V. 168. Article 117354.
  92. García-Atienza P., Martínez-Pérez-Cejuela H., Herrero-Martínez J.M., Arment S. Current trends in the sorbent-based extraction of illegal drugs from biofluids: Solid sorbents and configurations // Trends Anal. Chem. 2024. V. 172. Article 117599.
  93. Schettino L., Peris-Pastor G., Benedé J.L., Chisvert A. Advances in sample preparation a comprehensive review on the use of microextraction techniques in the analysis of cosmetic products // Adv. Sample Prep. 2022. V. 3. Article 100024.
  94. Salamat Q., Özen M.B., Soylak M. Green sample preparation techniques for trace analysis of organic species in cosmetic and personal care products // Microchem. J. 2025. V. 208. Article 112286.
  95. Ntorkou M., Zacharis C.K. Sorbent-based microextraction combined with GC-MS: A valuable tool in bioanalysis // Chemosensors. 2025. V. 13. P. 71.
  96. Dugheri S., Marrubini G., Mucci N., Cappelli G., Bonari A., Pompilio I., Trevisani L., Arcangeli G. A review of micro-solid-phase extraction techniques and devices applied in sample pretreatment coupled with chromatographic analysis // Acta Chromatogr. 2021. V. 33. P. 99.
  97. Martins R.O., de Araújo G.L., de Freitas C.S., Silva A.R., Simas R.C., Vaz B.G., Chaves A.R. Miniaturized sample preparation techniques and ambient mass spectrometry as approaches for food residue analysis // J. Chromatogr. A. 2021. V. 1640. Article 461949.
  98. Dugheri S., Mucci N., Cappelli G., Trevisani L., Bonari A., Bucaletti E., Squillaci D., Arcangeli G. Advanced solid-phase microextraction techniques and related automation: A review of commercially available technologies // J. Anal. Methods Chem. 2022. V. 2022. Article 8690569.
  99. Sartore D.M., Medina V.D.A., Bocelli M.D., Jordan-Sinisterra M., Santos-Neto Á.J., Lanças, F.M. Modern automated microextraction procedures for bioanalytical, environmental, and food analyses // J. Sep. Sci. 2023. V. 46. Article e2300215.
  100. Samadifar M., Yamini Y., Khataei M.M., Shirani M. Automated and semiautomated packed sorbent solid phase (micro) extraction methods for extraction of organic and inorganic pollutants // J. Chromatogr. A. 2023. V. 1706. Article 464227.
  101. Salamat Q., Gumus Z.P., Soylak M. Recent developments and applications of artificial intelligence in solid/liquid extraction studies // Trends Anal. Chem. 2025. V. 182. Article 118057.
  102. Bordin D.C.M., Alves M.N.R., de Campos E.G., De Martinis B.S. Disposable pipette tips extraction: Fundamentals, applications and state of the art: Sample preparation // J. Sep. Sci. 2016. V. 39. P. 1168.
  103. Seidi S., Tajik M., Baharfar M., Rezazadeh M. Micro solid phase extraction (pipette tip and spin column) and thin film solid phase microextraction: miniaturized concepts for chromatographic analysis // Trends Anal. Chem. 2019. V. 118. P. 810.
  104. Turoňová D., Krcmova L., Švec F. Application of microextraction in pipette tips in clinical and forensic toxicology // Trends Anal. Chem. 2021. V. 143. Article 116404.
  105. Sun H., Feng J., Han S., Ji X., Li, C. Feng J., Sun M. Recent advances in micro- and nanomaterial-based adsorbents for pipette-tip solid-phase extraction // Microchim. Acta 2021. V. 88. P. 189.
  106. Carasek E., Morés, L., Huelsmann R.D. Disposable pipette extraction: A critical review of concepts,applications, and directions // Anal. Chim. Acta. 2022. V. 1192. Article 339383.
  107. Kaykhaii M., Hashemi S.H., Gębicki J. Applications of metal organic framework adsorbents for pipette-tip micro solid-phase extraction // Trends Anal. Chem. 2024. V. 179. Article 117877.
  108. Abdel-Rehim M. Recent advances in microextraction by packed sorbent for bioanalysis // J. Chromatogr. A. 2010. V. 1217. P. 2569.
  109. Abdel-Rehim M. Microextraction by packed sorbent (MEPS): A tutorial // Anal. Chim. Acta. 2011. V. 701. P. 119.
  110. Alves G., Rodrigues, M., Fortuna A., Falcão A., Queiroz J. A critical review of microextraction by packed sorbent as a sample preparation approach in drug bioanalysis // Bioanalysis. 2013. V. 5. P. 1409.
  111. Pereira J., Gonçalves J., Alves V., Câmara J.S. Microextraction using packed sorbent as an effective and high-throughput sample extraction technique: Recent applications and future trends // Sample Preparation. 2013. V. 1. P. 38.
  112. Pereira J., Câmara J.S., Colmsjö A., Abdel-Rehim M. Microextraction by packed sorbent: An emerging, selective and high-throughput extraction technique in bioanalysis // Biomed. Chromatogr. 2014. V. 28. P. 839.
  113. Silva C., Cavaco C., Perestrelo R., Pereira J., Câmara J. Microextraction by packed sorbent (MEPS) and solid-phase microextraction (SPME) as sample preparation procedures for the metabolomic profiling of urine // Metabolites. 2014. V. 4. P. 71.
  114. Moein M.M., Said R., Abdel-Rehim M. Microextraction by packed sorbent // Bioanalysis. 2015. V. 7. P. 2155.
  115. Moein M.M., Abdel-Rehim A., Abdel-Rehim M. Microextraction by packed sorbent (MEPS) // Trends Anal. Chem. 2015. V. 67. P. 34.
  116. Yang L., Said R., Abdel-Rehim M. Sorbent, device, matrix and application in microextraction by packed sorbent (MEPS): A review // J. Chromatogr. B. 2017. V. 1043. P. 33.
  117. Pereira J.A.M., Gonçalves J., Porto-Figueira P., Figueira J.A., Alves V., Perestrelo R., Medina S., Câmara J.S. Current trends on microextraction by packed sorbent – Fundamentals, application fields, innovative improvements and future applications // Analyst. 2019. V. 144. P. 5048.
  118. Granados-Guzmán G., Díaz-Hernández M., Alvarez-Román R., Cavazos-Rocha N., Portillo-Castillo O.J. A brief review of the application of microextraction by packed sorbent for antibiotics analysis from biological, food, and environmental samples // Rev. Anal. Chem. 2023. V. 42. Article 20230057.
  119. Firoozichahak A., Soleymani-ghoozhdi D., Alizadeh S., Rahimpoor R. Microextraction by packed sorbents (MEPS): Fundamental principles and nanomaterial-based adsorbents // Trends Anal. Chem. 2024. V. 181. Article 118043.
  120. Andruch V., Kalyniukova A., Yordanova T., Płotka-Wasylka J., Vojteková V., Zengin G. Microextraction by packed sorbent: Uncommon detection techniques, sorbents, samples and analytes // Trends Anal. Chem. 2024. V. 176. Article 117769.
  121. Martins R.O., Borsatto J.V.B., Will C., Lanças F.M. Advancements in microextraction by packed sorbent: Insights into sorbent phases and automation strategies // Separations. 2025. V. 12. P. 11.
  122. Reyes-Garcés N., Gionfriddo E., Gómez-Ríos G.A., Alam M.N., Boyacl E., Bojko B., Singh V., Grandy J., Pawliszyn J. Advances in solid phase microextraction and perspective on future directions // Anal. Chem. 2018. V. 90. P. 302.
  123. Billiard K.M., Dershem A.R., Gionfriddo E. Implementing green analytical methodologies using solid-phase microextraction: A review // Molecules. 2020. V. 25. Article 5297.
  124. Jalili V., Barkhordari A., Ghiasvand A. A comprehensive look at solid-phase microextraction technique: A review of reviews // Microchem. J. 2020. V. 152. Article 104319.
  125. Nolvachai Y., Amaral M., Herron R., Marriott P. Solid phase microextraction – Expectations beyond design? // Green Anal. Chem. 2023. V. 4. Article 100048.
  126. Herrington J.S., German A.G., Myers C., Stidsen G., Bell D.S. Hunting molecules in complex matrices with SPME arrows: A review // Separations. 2020. V. 7. P. 12.
  127. Paiva A.C., Crucello J., de Aguiar Porto N., Hantao L.W. Fundamentals of and recent advances in sorbent-based headspace extractions // Trends Anal. Chem. 2021. V. 139. Article 116252.
  128. Lancioni C., Castells C., Candal R., Tascon M. Headspace solid-phase microextraction: Fundamentals and recent advances // Adv. Sample Prep. 2022. V. 3. Article 100035.
  129. Kataoka H. In-tube solid-phase microextraction: Current trends and future perspectives // J. Chromatogr. A. 2021. V. 1636. Article 461787.
  130. Olcer Y.A., Tascon M., Eroglu A.E., Boyacı E. Thin film microextraction: Towards faster and more sensitive microextraction // Trends Anal. Chem. 2019. V. 113. P. 93.
  131. Emmons R.V., Tajali R., Gionfriddo E. Development, optimization and applications of thin film solid phase microextraction (TF-SPME) devices for thermal desorption: A comprehensive review // Separations. 2019. V. 6. 3 P. 9.
  132. Peng S., Huang X., Huang Y., Huang Y., Zheng J., Zhu F., Xu J., Ouyang G. Novel solid-phase microextraction fiber coatings: A review // J. Sep. Sci. 2022. V. 45. P. 282.
  133. Rutkowska M. Solid supports and new advanced materials used in microextraction processes metal-organic framework-based solid-phase microextraction for air samples analysis: A mini-review // Trends Anal. Chem. 2024. V. 181. Part B. Article 118021.
  134. Omarova A., Bakaikina N.V., Muratuly A., Kazemian H., Baimatova N. A review on preparation methods and applications of metal–organic framework-based solid-phase microextraction coatings // Microchem. J. 2022. V. 175. Article 107147.
  135. Delińska K., Rakowska P.W., Kloskowski A. Porous material-based sorbent coatings in solid-phase microextraction technique: Recent trends and future perspectives // Trends Anal. Chem. 2021. V. 143. Article 116386.
  136. Feng J., Feng J., Ji X., Li C., Han S., Sun H., Sun M. Recent advances of covalent organic frameworks for solid-phase microextraction // Trends Anal. Chem. 2021. V. 137. Article 116208.
  137. Shahhoseini F., Azizi A., Bottaro C.S. A critical evaluation of molecularly imprinted polymer (MIP) coatings in solid phase microextraction devices // Trends Anal. Chem. 2022. V. 156. Article 116695.
  138. Jagirania M.S., Soylak M. A review: Recent advances in solid phase microextraction of toxic pollutants using nanotechnology scenario // Microchem. J. 2020. V. 159. Article 105436.
  139. Adeniji T.M., Haroon N., K.J. Stine K.J. Applications of nanomaterial coatings in solid-phase microextraction (SPME) // Processes. 2025. V. 13. Article 244.
  140. Hussain D., Naqvi S.T.R., Ashiq M.N., Najam-ul-Haq M. Analytical sample preparation by electrospun solid phase microextraction sorbents // Talanta. 2020. V. 208. Article 120413.
  141. Grecco C.F., Souza, I.D., Queiroz M.E.C. Novel materials as capillary coatings for in-tube solid-phase microextraction for bioanalysis // J. Sep. Sci. 2021. V. 44. P. 1662.
  142. Juanjuan F., Jiang Z., Ding Y., Li X., Sun M. Preparation and application of novel sorbents for in-tube solid-phase microextraction // Trends Anal. Chem. 2024. V. 181. Part A. Article 118047.
  143. Souza I.D., Oliveira I.G.C., Queiroz M.E.C. Innovative extraction materials for fiber-in-tube solid phase microextraction: A review // Anal. Chim. Acta. 2021. V. 1165. Article 238110.
  144. Ponce-Rodríguez H.D., Verdú-Andres J., Herraez-Hernandez R., Campíns-Falco P. Innovations in extractive phases for in-tube solid-phase microextraction coupled to miniaturized liquid chromatography: A critical review // Molecules. 2020. V. 25. Article 2460.
  145. Kataoka H., Ishizaki A., Saito K., Ehara K. Developments and applications of molecularly imprinted polymer-based in-tube solid phase microextraction technique for efficient sample preparation // Molecules. 2024. V. 29. Article 4472.
  146. Musarurwa H. Advances in thin film micro-extraction (TFME) of analytes using metal-organic frameworks, molecularly imprinted polymers, and polysaccharide composites as extraction phases // Microchem. J. 2024. V. 198. Article 110167.
  147. Krumplewski W., Rykowska I. New materials for thin-film solid-phase microextraction (TF-SPME) and their use for isolation and preconcentration of selected compounds from aqueous, biological and food matrices // Molecules. 2024. V. 29. Article 5025.
  148. Murtada K. Trends in nanomaterial-based solid-phase microextraction with a focus on environmental applications – A review // Trends Environ. Anal. Chem. 2020. V. 25. Article e00077.
  149. Keerthana S., Illanad G., Saketa S., Ghosh C. Recent advances in solid phase microextraction with various geometries in environmental analysis // RSC Adv. 2024. V. 14. P. 27608.
  150. Zheng J., Kuang Y., Zhou S., Gong X., Ouyang G. Latest improvements and expanding applications of solid-phase microextraction // Anal. Chem. 2023. V. 95. P. 218.
  151. Lan H., Hartonen K., Riekkola M.L. Miniaturised air sampling techniques for analysis of volatile organic compounds in air // Trends Anal. Chem. 2020. V. 126. Article 115873.
  152. Drabińska N., Marcinkowska M.A., Wieczorek M.N., Jeleń H.H. Application of sorbent-based extraction techniques in food analysis // Molecules. 2023. V. 28. Article 7985.
  153. . Agatonovic-Kustrin S., Gegechkori V., Kobakhidze T., Morton D. Solid-phase microextraction techniques and application in food and horticultural crops // Molecules. 2023. V. 28. Article 6880.
  154. Leszczyńska D., Hallmann A., Treder N., Bączek T., Roszkowska A. Recent advances in the use of SPME for drug analysis in clinical, toxicological, and forensic medicine studies // Talanta. 2024. V. 270. Article 125613.
  155. Manousi N., Tzanavaras P.D., Zacharis C.K. Bioanalytical HPLC applications of in-tube solid phase microextraction: A two-decade overview // Molecules. 2020. V. 25. Article 2096.
  156. Feng X., Kuang Y., Gan L., Zhou S., Zheng J., Ouyang G. Solid phase microextraction for the bioanalysis of emerging organic pollutants // Trends Anal. Chem. 2024. V. 177. Article 117786.
  157. Jalili V., Barkhordari A., Ghiasvand A. Solid-phase microextraction technique for sampling and preconcentration of polycyclic aromatic hydrocarbons: A review // Microchem. J. 2020. V. 157. Article 104967.
  158. Musarurwa H. Advances in thin film micro-extraction (TFME) of selected organic pollutants, and the evaluation of the sample preparation procedures using the AGREEprep green metric tool // Microchem. J. 2024. V. 203. Article 110938.
  159. Woźniczka K., Konieczynski P., Plenis A., Baczek T., Roszkowska A. SPME as a green sample-preparation technique for the monitoring of phytocannabinoids and endocannabinoids in complex matrices // J. Pharm. Anal. 2023. V. 13. Article 1117e1134.
  160. Zhou W., Wieczorek M.N., Javanmardi H., Pawliszyn J. Direct solid-phase microextraction-mass spectrometry facilitates rapid analysis and green analytical chemistry // Trends Anal. Chem. 2023. V. 166. Article 117167.
  161. Ntorkou M., Zacharis C.K. Sorbent-based microextraction combined with GC-MS: A valuable tool in bioanalysis // Chemosensors. 2025. V. 13. P. 71.
  162. Riboni N., Fornari F., Bianchi F., Careri M. Recent advances in in vivo SPME sampling // Separations. 2020. V. 7. Article 7010006.
  163. Ghosh C., Singh V., Grandy J., Pawliszyn J. Recent advances in breath analysis to track human health by new enrichment technologies // J. Sep. Sci. 2020. V. 43. P. 226.
  164. Yu M., Roszkowska A., Pawliszyn J. In vivo solid-phase microextraction and applications in environmental sciences // ACS Environ. Au. 2021. V. 2. P. 30.
  165. Hu B., Ouyang G. In situ solid phase microextraction sampling of analytes from living human objects for mass spectrometry analysis // Trends Anal. Chem. 2021. V. 143. Article 116368.
  166. Queiroz M.E.C., Souza I.D., de Oliveira, I.G., de Grecco C.F. In vivo solid phase microextraction for bioanalysis // Trends Anal. Chem. 2022. V. 153. Article 116656.
  167. Li N., Zhang Z., Li G. Recent advance on microextraction sampling technologies for bioanalysis // J. Chromatogr. A. 2024. V. 1720. Article 464775.
  168. Sevgen S., Kara G., Kir A.S., Şahin A., Boyac E. A critical review of bioanalytical and clinical applications of solid phase microextraction // J. Pharm. Biomed. Anal. 2025. V. 252. Article 116487.
  169. Hemmati M., Nix C., Crommen J., Servais A.-C., Fillet M. Benefits of microsampling and microextraction for metabolomics studies // Trends Anal. Chem. 2020. V. 127. Article 115899.
  170. Gong X., Lin S., Huang X., Peng S., Shen M., Ouyang S., Zheng J., Xu J., Ouyang G. Applications of in vivo SPME based on mass spectrometry for environmental pollutants analysis and non-target metabolomics: A review // Green Anal. Chem. 2022. V. 1. Article 100004.
  171. Młynarczyk M., Belka M., Hewelt-Belka W. Novel materials and approaches for solid-phase (micro) extraction in LC-MS-based metabolomics // Trends Anal. Chem. 2024. V. 180. Article 117941.
  172. Kawaguchi M., Ito R., Saito K., Nakazawa H. Novel stir bar sorptive extraction methods for environmental and biomedical analysis // J. Pharm. Biomed. Anal. 2006. V. 40. P. 500.
  173. David F., Sandra P. Stir bar sorptive extraction for trace analysis // J. Chromatogr. A. 2007. V. 1152. P. 54.
  174. Sánchez-Rojas F., Bosch-Ojeda C. Cano-Pavón J.M. A review of stir bar sorptive extraction // Chromatographia. 2009. V. 69. P. 79.
  175. Prieto A., Basauri O., Rodil R., Usobiaga A., Fernández L.A., Etxebarria N., Zuloaga O. Stir-bar sorptive extraction: A view on method optimisation, novel applications, limitations and potential solutions // J. Chromatogr. A. 2009. V. 1217. P. 2642.
  176. Kawaguchi M., Takatsu A., Ito R., Nakazawa H. Applications of stir-bar sorptive extraction to food analysis // Trends Anal. Chem. 2013. V. 45. P. 280.
  177. Gilart N., Marcé R.M., Borrull F., Fontanals N. New coatings for stir-bar sorptive extraction of polar emerging organic contaminants // Trends Anal. Chem. 2014. V. 54. P. 11.
  178. Camino-Sánchez F. J., Rodríguez-Gómez R., Zafra-Gómez A., Santos-Fandila A., Vílchez J.L. Stir bar sorptive extraction: Recent applications, limitations and future trends // Talanta. 2014. V. 130. P. 388.
  179. He M., Chen B., Hu B. Recent developments in stir bar sorptive extraction microextraction techniques // Anal. Bioanal. Chem. 2014. V. 406. P. 2001.
  180. Nogueira J.M.F. Stir-bar sorptive extraction: 15 years making sample preparation more environment-friendly // Trends Anal. Chem. 2015. V. 71. P. 214.
  181. Ochiai N., Sasamoto K., David F., Sandra P. Recent developments of stir bar sorptive extraction for food applications: Extension to polar solutes // J. Agric. Food Chem. 2018. V. 66. P. 7249.
  182. David F., Ochiai N., Sandra P. Two decades of stir bar sorptive extraction: A retrospective and future outlook // Trends Anal. Chem. 2019. V. 112. P. 102.
  183. Hasan C.K., Ghiasvand A., Lewis T.W., Nesterenko P.N., Paull B. Recent advances in stir-bar sorptive extraction: Coatings, technical improvements, and applications // Anal. Chim. Acta. 2020. V. 1139. P. 222.
  184. Hashemi S.H., Kaykhaii M. Nanoparticle coatings for stir bar sorptive extraction, synthesis, characterization and application // Talanta. 2021. V. 221. Article 121568.
  185. He M., Wang, Y., Zhang Q., Zang L., Chen B., Hu B. Stir bar sorptive extraction and its application // J. Chromatogr. A. 2021. V. 1637. Article 461810.
  186. Vallez-Gomis V., Escribano J. G., Benedé J.L., Giokas D.L., Chisvert A., Salvador A. Fundamentals and applications of stir bar sorptive dispersive microextraction: A tutorial review // Anal. Chim. Acta. 2021. V. 1153. Article 338271.
  187. Kabir A., Samanidou V. Fabric phase sorptive extraction: A paradigm shift approach in analytical and bioanalytical sample preparation // Molecules. 2021. V. 26. Article 865.
  188. Samanidou V., Kabir A. Novel sorptive sample preparation techniques for separation science // LCGC Europe. 2023. V. 36. P. 79.
  189. Manousi N., Płotka-Wasylka J., Samanidou V. Novel sorptive extraction techniques in bioanalysis evaluated by blue applicability grade index: The paradigm of fabric phase sorptive extraction and capsule phase microextraction // Trends Anal. Chem. 2024. V. 172. Article 117586.
  190. Jain B., Jain R. Kabir A., Alharthi S., AbdElrahman M., Ghoneim M.M., Sharma S., Yahaya N., Rashid S. Modern sorbent-based sample preparation methods for the determination of analytes of forensic interest: A dual-tool approach for evaluation of greenness and practical utility // Trends Anal. Chem. 2025. V. 184. Article 118129.

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML
Жүктеу

© Russian Academy of Sciences, 2025