The possibilities of using polymer composite materials to protect technological equipment for oil storage from the formation of pyrophoric deposits

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

Formulations of seven polyurea-based composite materials are proposed as a matrix to protect the inner surface of oil storage equipment from the formation of pyrophoric deposits. Mechanical or mechano-chemically activated mixtures of activated carbon with titanium dioxide and shungite with titanium dioxide were used as composite fillers. It has been established that the use of the developed composite coatings makes it possible to reduce the rate of hydrogen sulfide corrosion of steel by 26–70 times. It has been shown that coatings in which the filler is an ultrasound-treated mixture of titanium dioxide and activated carbon can perform not only a protective barrier function, but also provide oxidative desulfurization of oil vapor.

About the authors

S. A. Syrbu

Ivanovo Fire and Rescue Academy; MIREA – Russian Technological University

Email: syrbue@yandex.ru
Ivanovo, Russia; Moscow, Russia

A. S. Mitrofanov

Ivanovo Fire and Rescue Academy

Email: syrbue@yandex.ru
Ivanovo, Russia

N. A. Torshinina

Krestov Institute of Solution Chemistry, Russian Academy of Sciences; Ivanovo State University of Chemical Technology

Email: syrbue@yandex.ru
Ivanovo, Russia; Ivanovo, Russia

A. F. Chudakova

Ivanovo Fire and Rescue Academy

Email: syrbue@yandex.ru
Ivanovo, Russia

A. G. Azovtsev

Ivanovo Fire and Rescue Academy

Email: syrbue@yandex.ru
Ivanovo, Russia

N. A. Taratanov

Ivanovo Fire and Rescue Academy

Email: syrbue@yandex.ru
Ivanovo, Russia

A. G. Naumov

Ivanovo Fire and Rescue Academy

Author for correspondence.
Email: syrbue@yandex.ru
Ivanovo, Russia

References

  1. Barton L. L., Fauque G. D. // Adv. Appl. Microbiol. 2009. V. 68. P. 41. https://doi.org/10.1016/s0065-2164(09)01202-7
  2. Reformatskaya I.I., Begishev I.R., Ascheulova I.I. et al. // Russ. J. Phys. Chem. A. 2023. V. 97. № 4. P. 781. https://doi.org/10.1134/S036024423040234
  3. Reformatskaya I.I., Petrilin D.A., Ascheulova I.I. // Occupational Safety in Industry. 2024. №. 7. P. 74. https://doi.org/10/24000/0409-2961-2024-7-74-80
  4. Vasiliev A.A., Dzidziguri E.L., Efimov M.N. et al. // Russ. J. Phys. Chem. B. 2021. V. 15. P. 381. https://doi.org/10.1134/S1990793121030313
  5. Zhukov A.M., Solodilov V.I., Tretyakov I.V. et al. // Russ. J. Phys. Chem. B. 2022. V. 16. P. 926. https://doi.org/10.1134/S199079312205013X
  6. Taratanov N.A., Syrbu S.A. // ChemChemTech. 2021. V. 64. № 12. P. 76. https://doi.org/10.6060/ivkkt.20216412.6395
  7. Myasoedova V.V., Golobokov D.A. // Russ. J. Phys. Chem. B. 2024. V. 18. P. 773. https://doi.org/10.1134/S1990793124700039
  8. Morozov E.V., Il′ichev A.V., Bouznik V.M. // Russ. J. Phys. Chem. B. 2023. V. 17. P. 1361. https://doi.org/10.1134/S1990793123060064
  9. Bakirova E.R., Lazdin R.Yu., Shurshina A.S. et al. // Russ. J. Phys. Chem. B. 2024. V. 18. P. 549. https://doi.org/10.1134/S1990793124020040
  10. Sitdikova A.V., Sadretdinov I.F., Alyabyev A.S. et al. // Petroleum Engineering. 2012. № 2. P. 479. http://www.ogbus.ru
  11. GOST ISO 9226-2022. Corrosion of metals and alloys. The corrosive aggressiveness of the atmosphere. Methods for determining the corrosion rate of standard samples used to assess corrosion aggressiveness. Moscow: Russian Institute of Standardization, 2022.
  12. Azovtsev A.G., Syrbu S.A. // Modern high-tech technologies – regional application. 2020. № 2 (62). P. 90.
  13. Syrbu S.A., Azovtsev A.G., Taratanov N.A. Protective composition against the formation of pyrophoric deposits formed by hydrogen sulfide compounds with iron. Patent № 2737908 RF // Rospatent. 2020. № 24.
  14. Mitrofanov A.S., Syrbu S.A., Azovtsev A.G. // Modern Problems Civil Protection. 2022. Issue 4 (45). P. 93.
  15. Romanov S.V., Botvinova O.A., Timakov E.A. et al. // Fine Сhem. Technol. 2021. V 16. № 2. P. 176. https://doi.org/10.32362/2410-6593-2021-16-2-176-183
  16. Gonik A.A. Corrosion of oilfield equipment and measures to prevent it. 2nd ed., revised and additional. M.: Nedra, 1976.

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2025 Russian Academy of Sciences